Formation of Phosphate Derivatives by the Reaction of Propyl and Allyl Halides with Phosphorus Trichloride and Oxygen

Y Okamoto, T Okada, H Sakurai

Index: Okamoto,Y. et al. Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 484 - 487

Full Text: HTML

Citation Number: 6

Abstract

In addition to phosphonyl dichlorides, a significant amount of phosphoryl dichlorides was obtained by the reaction of propyl and allyl halides with phosphorus trichloride in oxygen atmosphere. Formation of the P–O–C bond can be explained by a scheme involving a preferential reaction of the bridged intermediate radical with oxygen.