A novel method for the separation of bis (α-hydroxyalkyl) phosphinic acid diastereoisomers via formation of novel cyclic phosphinic acids

B Kaboudin, H Haghighat…

文献索引：Kaboudin; Balakrishna Synthetic Communications, 2001 , vol. 31, # 18 p. 2773 - 2776

被引用次数: 30

摘要

The reaction of aromatic and aliphatic aldehydes with hypophosphorus acid under microwave irradiation was examined. The reaction gave a mixture of a racemic pair of bis (α- hydroxyalkyl) phosphinic acids and acetal derivatives from the corresponding bis (α-

~85%

~69%

~80%

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