Synthetic communications

Efficient synthesis of tolunitriles by selective ammoxidation

G Xie, Q Zheng, C Huang, Y Chen

文献索引：Xie, Guangyong; Zheng, Qiong; Huang, Chi; Chen, Yuanyin Synthetic Communications, 2003 , vol. 33, # 7 p. 1103 - 1107

全文：HTML全文

被引用次数: 4

摘要

Abstract Tolunitriles have been efficiently synthesized by selective ammoxidation of methylbenzyl chlorides prepared with chlorination of xylenes. In comparison with ammoxidation of xylenes themselves, the reaction temperature of ammoxidation of methylbenzyl chlorides has been lowered more than 100° C and the selectivity forming mono-nitriles is almost 100%.