Preparation of aryl chlorides from phenols

…, DA Bak, PE Timony, A Leone-Bay

文献索引：Bay, Elliott; Bak, David A.; Timony, Peter E.; Leone-Bay, Andrea Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3415 - 3417

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被引用次数: 16

摘要

Wiley and co-workers2 produced bromobenzene by heating a mixture of phenol and triphenylphosphine dibromide at 200" C until the evolution of hydrogen bromide stopped. Bromobenzene was obtained in 92% yield. In this case, triphenylphosphine oxide was formed as a byproduct and, again, a separation step was needed. Our continued work in the area of organophosphorus chemistry has led us to the discovery that phenylphosphorus ...