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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Synthesis of a series of novel polycyclic aromatic systems: Isomers of benz [a] anthracene containing a cyclopenta-fused ring

R Sangaiah, A Gold, GE Toney

文献索引：Sangaiah, R.; Gold, A.; Toney, G. E. Journal of Organic Chemistry, 1983 , vol. 48, # 10 p. 1632 - 1638

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被引用次数: 45

摘要

The four possible isomers of benz [a] anthracene containing a cyclopenta-fused ring have been synthesized and characterized. Thew systems are of interest for structureactivity studies in bioactivation because of their predicted high level of activity. Formation of fused five-membered rings by intramolecular cyclodehydration, often difficult to accomplish, was found to be smoothly effected in anhydrous HF, provided the reactivity index (Nt) for the ...

7-CHLOROMETHYL BENZ(a)ANTHRACENE结构式

7-CHLOROMETHYL ...

~85%

苯并[a]蒽-7-乙腈结构式

苯并[a]蒽-7-乙腈

苯并[a]蒽-7-乙腈结构式

苯并[a]蒽-7-乙腈

~85%

苯并[a]蒽-7-乙酸结构式

苯并[a]蒽-7-乙酸

7-CHLOROMETHYL BENZ(a)ANTHRACENE结构式

7-CHLOROMETHYL ...

~%

苯并[a]蒽-7-乙酸结构式

苯并[a]蒽-7-乙酸

5-methylbenzo[a]anthracene-7,12-dione结构式

5-methylbenzo[a...

~96%

5-甲基苯并[A]蒽结构式

5-甲基苯并[A]蒽

1,2-dihydrocyclopenta[no]tetraphen-1-ol结构式

1,2-dihydrocycl...

~%

Benzaceanthrylene结构式

Benzaceanthrylene

5,6,8,9-四氢苯并[a]蒽-11(10H)-酮结构式

5,6,8,9-四氢苯并[a]...

~%

Benzaceanthrylene结构式

Benzaceanthrylene

4,5-Dihydrobenz[k]acephenanthrylenequinone结构式

4,5-Dihydrobenz...

~99%

4,5-DIHYDRO-BENZ(K)ACEPHENANTHRYLENE结构式

4,5-DIHYDRO-BEN...

2-(4-methylnaphthalene-1-carbonyl)benzoic acid结构式

2-(4-methylnaph...

~52%

5-methylbenzo[a]anthracene-7,12-dione结构式

5-methylbenzo[a...

HIV-1 Nef-IN-1结构式

~69%

Benz[a]anthracen-8(9H)-one, 10,11-dihydro-结构式

Benz[a]anthrace...

1-Hydroxy-1,2-dihydrobenz[j]aceanthrylene结构式

1-Hydroxy-1,2-d...

~62%

benzo[j]aceanthrylene结构式

benzo[j]aceanth...

4,5-DIHYDRO-BENZ(K)ACEPHENANTHRYLENE结构式

4,5-DIHYDRO-BEN...

~71%

benz[k]acephenanthrylene结构式

benz[k]acephena...

4,5-dihydrocyclopenta[de]tetraphen-4-ol结构式

4,5-dihydrocycl...

~%

benz[k]acephenanthrylene结构式

benz[k]acephena...

5-methylbenzo[a]anthracene-7,12-dione结构式

5-methylbenzo[a...

~%

benz[k]acephenanthrylene结构式

benz[k]acephena...

5-甲基苯并[A]蒽结构式

5-甲基苯并[A]蒽

~%

benz[k]acephenanthrylene结构式

benz[k]acephena...

Ethyl-1,2-benzanthracen-5-acetat结构式

Ethyl-1,2-benza...

~90%

Benz[a]anthracene-8-acetic acid结构式

Benz[a]anthrace...

Benz[a]anthracen-8(9H)-one, 10,11-dihydro-结构式

Benz[a]anthrace...

~%

Benz[a]anthracene-8-acetic acid结构式

Benz[a]anthrace...

HIV-1 Nef-IN-1结构式

~%

Benz[a]anthracene-8-acetic acid结构式

Benz[a]anthrace...

ethyl 2-(8-hydroxy-8,9,10,11-tetrahydrotetraphen-8-yl)acetate结构式

ethyl 2-(8-hydr...

~%

Benz[a]anthracene-8-acetic acid结构式

Benz[a]anthrace...