Reactions of Iminium Ions with Michael Acceptors through a Morita–Baylis–Hillman??Type Reaction: Enantiocontrol and Applications in Synthesis

…, JG de Vries, VK Aggarwal

文献索引：Myers, Eddie L.; De Vries, Johannes G.; Aggarwal, Varinder K. Angewandte Chemie - International Edition, 2007 , vol. 46, # 11 p. 1893 - 1896

全文：HTML全文

被引用次数: 62

摘要

Eddie L. Myers, Johannes G. de Vries, and Varinder K. Aggarwal* α-Functionalization of alkenes activated by electron-withdrawing groups (EWGs) encompass an important CÀC bondforming strategy in organic synthesis, and can be realized in one of three ways: a) metal-catalyzed functionalization of αhalogeno [1] or α-metallo substrates;[2] b) a vinylogous enolization, α-alkylation, and isomerization sequence;[3] or c) nucleophilic catalysis: the ...