2-Bromoethylperoxy and 2-bromo-1-methylpropylperoxy radicals: ultraviolet absorption spectra and self-reaction rate constants at 298 K

JN Crowley, GK Moortgat

文献索引：Crowley, John N.; Moortgat, Geert K. Journal of the Chemical Society, Faraday Transactions, 1992 , vol. 88, # 17 p. 2437 - 2444

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被引用次数: 23

摘要

The self-reaction rate constants and UV absorption spectra of two brominated peroxy radicals, BrCH2CH2O2 (2-bromoethylperoxy) and (CH3) BrCHCH (CH3) O2 (2-bromo-1- methylpropylperoxy) have been measured using the molecular modulation technique, Self- reaction rate constants (Kobc) of (6.2±1.2)× 10–12 and (9.6±1.9)× 10–13 cm3 molecule–1 s– 1 were obtained for BrCH2CH2O2 and (CH3) BrCHCH (CH3) O2, respectively. In both ...