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Gas-phase Lewis acid-base interactions. An experimental determination of cyanide binding energies from ion cyclotron resonance and high-pressure mass …

…, JE Szulejko, TB McMahon

文献索引:Larson, J. W.; Szulejko, J. E.; McMahon, T. B. Journal of the American Chemical Society, 1988 , vol. 110, # 23 p. 7604 - 7609

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被引用次数: 36

摘要

Conclusion Ion cyclotron resonance, high-pressure mass spectrometric, and collision- induced decomposition experiments as well as ab initio calculations have been used to investigate the gas-phase ionmolecule reactions occurring in nitrogen trifluoride-methane mixtures. The major feature of this chemistry is the production of nitrogen protonated hydrogen cyanide from the reaction of both