Influence of fatty acid desaturation on spontaneous acyl migration in 2-monoacylglycerols

…, JA Laszlo, M Appell, KE Vermillion, KO Evans

文献索引：Compton, David L.; Laszlo, Joseph A.; Appell, Michael; Vermillion, Karl E.; Evans, Kervin O. JAOCS, Journal of the American Oil Chemists' Society, 2012 , vol. 89, # 12 p. 2259 - 2267

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被引用次数: 5

摘要

Abstract The effect of desaturation from the C9 to the C15 carbon of 2-monoacylglycerol (2- MAG) fatty acids on spontaneous acyl migration is described. Three 2-MAG species, 2- monooleoylglycerol (C18: 1 cis-Δ9), 2-monolinoleoylglycerol (C18: 2 cis-Δ9, 12), and 2- monolinolenoylglycerol (C18: 3 cis-Δ9, 12, 15) were synthesized by lipase-catalyzed ethanolysis of their respective triacylglycerols and isolated in> 60% yield and at 2-MAG ...