Preparation of 2-oxygen derivatives of 1, 2-oxaborolane from 2-allyloxy-1, 2-oxaborolane

…, L Weiming, Z Gaoyi, D Hongxun, L Shaofang

文献索引：Weike, Zhou; Weiming, Lo; Gaoyi, Zhang; Hongxun, Ding; Shaofang, Liang Journal of Organometallic Chemistry, 1990 , vol. 387, # 2 p. 131 - 146

全文：HTML全文

被引用次数: 0

摘要

Abstract 2-Allyloxy-1, 2-oxaborolane (V), readily obtained by hydroboration of allyl alcohol with borane reagents such as KBH 4 HOAc, was used as a key reactant in the synthesis of a series of 2-oxygen derivatives of 1, 2-oxaborolane. 2-Allyl-1, 2-oxaborolane (XXIII) and 2- hydro-1, 2-oxaborolane dimethylsulfide complex (XXIV), prepared from the reaction of V with allylmagnesium bromide and dimethylsulfideborane complex (BMS) respectively, were ...