Preparation of 2-oxygen derivatives of 1, 2-oxaborolane from 2-allyloxy-1, 2-oxaborolane

…, L Weiming, Z Gaoyi, D Hongxun, L Shaofang

Index: Weike, Zhou; Weiming, Lo; Gaoyi, Zhang; Hongxun, Ding; Shaofang, Liang Journal of Organometallic Chemistry, 1990 , vol. 387, # 2 p. 131 - 146

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Abstract

Abstract 2-Allyloxy-1, 2-oxaborolane (V), readily obtained by hydroboration of allyl alcohol with borane reagents such as KBH 4 HOAc, was used as a key reactant in the synthesis of a series of 2-oxygen derivatives of 1, 2-oxaborolane. 2-Allyl-1, 2-oxaborolane (XXIII) and 2- hydro-1, 2-oxaborolane dimethylsulfide complex (XXIV), prepared from the reaction of V with allylmagnesium bromide and dimethylsulfideborane complex (BMS) respectively, were ...

Synthesis and evaluation of novel α-amino cyclic boronates a...

[Li, Xianfeng; Zhang, Yong-Kang; Liu, Yang; Ding, Charles Z.; Li, Qun; Zhou, Yasheen; Plattner, Jacob J.; Baker, Stephen J.; Qian, Xuelei; Fan, Dazhong; Liao, Liang; Ni, Zhi-Jie; White, Gemma V.; Mordaunt, Jackie E.; Lazarides, Linos X.; Slater, Martin J.; Jarvest, Richard L.; Thommes, Pia; Ellis, Malcolm; Edge, Colin M.; Hubbard, Julia A.; Somers, Don; Rowland, Paul; Nassau, Pamela; McDowell, Bill; Skarzynski, Tadeusz J.; Kazmierski, Wieslaw M.; Grimes, Richard M.; Wright, Lois L.; Smith, Gary K.; Zou, Wuxin; Wright, Jon; Pennicott, Lewis E. Bioorganic and Medicinal Chemistry Letters, 2010 , vol. 20, # 12 p. 3550 - 3556]