Photochemistry of cyclopropene derivatives. Synthesis and photorearrangement of a 3-acyl-substituted cyclopropene

A Padwa, M Akiba, CS Chou…

文献索引：Padwa, Albert; Akiba, Mitsuo; Chou, Chuen S.; Cohen, Leslie Journal of Organic Chemistry, 1982 , vol. 47, # 2 p. 183 - 191

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被引用次数: 30

摘要

Two different approaches toward the synthesis of a 3-acyl-substituted 1, 2, 3- triphenylcyclopropene were inveatigatd. The first involved beating triphenylcyclopropenyl perchlorate with the anion derived from 1, 3-dithiane followed by hydrolysis of the resulting dithioacetal. Unfortunately, all attempts to obtain a carbonyl compound from the hydrolysis failed. The only product obtained corresponded to a 1, 2-diphenyl-1, 2-diacyl-substituted ...