A Vanadium??Based Chemical Oscillator: Identification of Chemical Species Responsible for the Redox Reaction and Construction of a Simplified Model

K Kanamori, H Kataoka…

文献索引：Kanamori, Kan; Kataoka, Hiroshi; Matsugo, Seiichi European Journal of Inorganic Chemistry, 2012 , # 29 p. 4570 - 4573

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被引用次数: 1

摘要

Abstract To identify the chemical species involved in a unique, vanadium-based chemical oscillator reaction, products derived from indole in the oscillation solution were isolated and characterized. NMR and mass spectra showed that 3, 3-dichloro-2-oxoindole and isatin were formed during the oscillation process. The formation of these two compounds suggests that peroxo species such as CHCl 2 OO· and CHCl 2 OOH play a key role in the ...