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Small-Ring Compounds. XLVI. Stabilized Cyclopropylcarbinyl Anions. A Retro Cyclopropylcarbinyl-Allylcarbinyl Rearrangement1

A Maercker, JD Roberts

文献索引:Maercker,A.; Roberts,J.D. Journal of the American Chemical Society, 1966 , vol. 88, # 8 p. 1742 - 1759

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被引用次数: 64

摘要

Abstract: The cyclopropylcarbinyl anion is stabilized by a phenyl group attached to the carbinyl carbon toward ring opening, provided that potassium or sodium is the counterion. Replacement of potassium by lithium or magnesium in ether leads to immediate ...