Small-Ring Compounds. XLVI. Stabilized Cyclopropylcarbinyl Anions. A Retro Cyclopropylcarbinyl-Allylcarbinyl Rearrangement1

A Maercker, JD Roberts

Index: Maercker,A.; Roberts,J.D. Journal of the American Chemical Society, 1966 , vol. 88, # 8 p. 1742 - 1759

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Citation Number: 64

Abstract

Abstract: The cyclopropylcarbinyl anion is stabilized by a phenyl group attached to the carbinyl carbon toward ring opening, provided that potassium or sodium is the counterion. Replacement of potassium by lithium or magnesium in ether leads to immediate ...