Cyclopentylphenylcarbinyl cation system

SA Roman, WD Closson

文献索引：Roman,S.A.; Closson,W.D. Journal of the American Chemical Society, 1969 , vol. 91, # 7 p. 1701 - 1709

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摘要

Abstract: Two T and two a routes to the cyclopentylphenylcarbinyl cation have been examined with respect to the effect of the ionization pathway on the composition of acetolysis products formed. Unlike most other systems investigated this benzylic cation yields the most elimination product by the T routes. Deamination of cyclo- pentylphenylcarbinylamine in acetic acid yields products where the substitution/ ...