Electroreductive cyclization reactions of 6-chloro-1-phenyl-1-hexyne and 6-chloro-1-phenyl-1, 2-hexadiene at a mercury cathode in dimethylformamide

WM Moore, A Salajegheh…

文献索引：Moore,W.M. et al. Journal of the American Chemical Society, 1975 , vol. 97, # 17 p. 4954 - 4960

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被引用次数: 28

摘要

Abstract: A study of the electrochemical behavior of 6-chloro-I-phenyl-I-hexyne at a mercury cathode in dimethylformamide containing 0.1 F tetra-n-butylammonium perchlorate has been undertaken. Two polarographic waves are observed for this compound: the first wave is due to reduction of the carbon-carbon triple bond, whereas the second step results from si- multaneous reductions of the carbon-chlorine bond of the starting material and ...