Journal of the American Chemical Society

Macro Rings. XXV. Fate of Carbonium Ions Held in π-Clouds of Benzene Rings

DJ Cram, M Goldstein

文献索引：Cram,D.J.; Goldstein,M. Journal of the American Chemical Society, 1963 , vol. 85, p. 1063 - 1074

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被引用次数: 30

摘要

Solvolysis Products.-The acetolysis products of tosylates XXXVII and XXXVIII were examined, and the products are indicated in Chart 11. The product studies were made in dry acetic acid solutions 0.02 M in substrate and 0.022 M in sodium acetate, whereas no acetate was added to the kinetic runs. The balance of the four products proved to be essentially the same in the absence and presence of the added base, a fact that suggests the products ...