Many-Membered Carbon Rings. XXIII. Restricted Rotation in a Simple Paracyclophane1-3

AT Blomquist, RE STAHL, YC MEINWALD…

文献索引：Blomquist,A.T. et al. Journal of Organic Chemistry, 1961 , vol. 26, # 6 p. 1687 - 1691

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被引用次数: 30

摘要

The objective of this investigation was to demonstrate hindered rotation about single bonds in certain simple paracyolophanes. This purpose waa achieved by thereaolution of a suitable+ substituted paracyclophane which had ten carbon atom in its para-bridge, as exemplified by the compound [10] paracyclophane-l2-carboxylic acid. This acid waa synthesized in three steps from [10) paracyclophane:[101 paracyclophane-+ 12- ...