Kinetic Study on Aminolysis of Y-Substituted-Phenyl X-Substituted-Benzoates: Effects of Substituents X and Y on Reactivity and Reaction Mechanism

SH Jeon, HS Kim, YJ Han, MY Kim…

文献索引：Jeon, Seong Hoon; Kim, Hyun Soo; Han, Young Joon; Kim, Min-Young; Um, Ik-Hwan Bulletin of the Korean Chemical Society, 2014 , vol. 35, # 2 p. 471 - 476

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被引用次数: 2

摘要

Abstract A kinetic study on aminolysis of 2-chloro-4-nitrophenyl X-substituted-benzoates (2a- k) in 80 mol% DMSO at is reported. The Br nsted-type plot for the reactions of 2-chloro-4- nitrophenyl benzoate (2g) with a series of cyclic secondary amines curves downward (eg,, ...