Conjugated Systems in the Anthracene Series. IV. Transannular Anthranol Peroxides

PL Julian, W Cole, G Diemer

文献索引：Julian; Cole; Diemer Journal of the American Chemical Society, 1945 , vol. 67, p. 1721,1723

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被引用次数: 7

摘要

These peroxides were all prepared by 1, 6-addition of the appropriate Grignard reagent to methyleneanthrone (I) and treatment of the resulting anthranol with atmospheric oxygen. Benzylanthranol peroxide was also prepared by catalflc reduction (1, c-addition of hydrogen) to benzalanthrone in acetone solution, followed by treatment with oxygen. Surprisingly stable crystalline solids at ordinary temperatures, these peroxides undergo ...