Attempted cyclization of an epoxide. Elimination of an epoxide

I Rothberg, L Schneider, S Kirsch…

文献索引：Rothberg, Irvin; Schneider, Louis; Kirsch, Sheldon; OFee, Robert Journal of Organic Chemistry, 1982 , vol. 47, # 13 p. 2675 - 2676

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被引用次数: 3

摘要

Nv. 5 7 tetrahydrofuran. GLC examination of the products showed a complex mixture of 15 different compounds. None was present as a major component. There was no cyclohexanol or cyclopentylmethanol produced, which would have been the expected cyclization products. Clearly, for cyclization to occur there are very severe restrictions on the geometry of the chloro epoxide. We investigated whether the chloromethylene group must be ...