The Journal of Organic Chemistry

Dehydrohalogenation of vic-dihaloalkanes over silica gel

AR Suarez, MR Mazzieri

文献索引：Suarez, Angela R.; Mazzieri, Maria R. Journal of Organic Chemistry, 1987 , vol. 52, # 6 p. 1145 - 1147

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被引用次数: 8

摘要

The use of silica gel and other solids with active surfaces as catalysts for gas-phase dehydrohalogenation at high temperatures (200-500" C) is well-known. An El or like El mechanism is generally accepted for reactions over silica By contrast, there is little information about reactions performed in solution. Incremona and Martin3 reported the 2d formation (56% yield) by passing Id through a column of Fluorosil with carbon ...