Tetrahedron

A new entry of highly nucleophilic CHBr 3–TiCl 4–Mg system for the stereoselective synthesis of 1-alkenyl bromides

YR Bhorge, SH Chang, CT Chang, TH Yan

文献索引：Bhorge, Yeshwant Ramchandra; Chang, Su-Haur; Chang, Cheng-Ta; Yan, Tu-Hsin Tetrahedron, 2012 , vol. 68, # 24 p. 4846 - 4851

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被引用次数: 7

摘要

Formation of C C bonds by means of metallo–carbenes constitutes a particularly valuable strategy. The importance of alkenyl bromides as valuable building precursors in molecular transformations, such as Suzuki and Stille couplings has stimulated much interest in the development of new efficient methodology for their construction. Among the most direct approach to such systems involves the bromoolefination of aldehydes using ...