Tetrahedron

Chiral acetals in organic synthesis: Regioselective synthesis of 2-and 3-hydroxy acetals from 2, 3-olefinic acetals. Reinvestigation and further applications

YD Vankar, MV Reddy, NC Chaudhuri

文献索引：Vankar, Yashwant D.; Reddy, M. Venkatram; Chaudhuri, Narayan C. Tetrahedron, 1994 , vol. 50, # 37 p. 11057 - 11078

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被引用次数: 5

摘要

Achiral as well as chiral 2, 3-olefinic acetals are converted into 2-and 3-hydroxy acetals via LAH reduction of the corresponding epoxides and via bromohydrins followed by TBTH reductions respectively. Synthesis of 1, 3-diones is described. Compounds from chiral systems are further utilized for asymmetric synthesis.

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Alicyclic diketones and diols—: The preparation and properti...

[Vankar, Yashwant D.; Chaudhuri, Narayan C.; Rao, C. Trinadha Tetrahedron Letters, 1987 , vol. 28, # 5 p. 551 - 554]

The Monoethylene Ketal of 1, 3-Cyclohexanedione

[Cronyn; Goodrich Journal of the American Chemical Society, 1952 , vol. 74, p. 3331]

Alicyclic diketones and diols—: The preparation and properti...

[Vankar, Yashwant D.; Chaudhuri, Narayan C.; Rao, C. Trinadha Tetrahedron Letters, 1987 , vol. 28, # 5 p. 551 - 554]