A series of triazole-linked ester-type glycolipids were efficiently prepared via a two-step sequence involving microwave accelerated 'click'chemistry and debenzylation. All carbon chain length varied O-alkynyl fatty esters used to couple with 1-azido-tetra-O-benzyl-β-d- glucoside showed excellent tolerance to the microwave-assisted 1, 3-dipolar cycloaddition (click reaction), forming the unique cycloadducts in almost quantitative yields of 92.9–99.0 ...