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Reactions of Organoazides with Nickel Alkyls. Syntheses and Reactions of Nickel (II) Amido Complexes

PT Matsunaga, CR Hess…

文献索引:Matsunaga, Phillip T.; Hess, Corinna R.; Hillhouse, Gregory L. Journal of the American Chemical Society, 1994 , vol. 116, # 8 p. 3665 - 3666

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被引用次数: 32

摘要

Amido complexes (L” M-NR2) of late transition metals are rare, but they are interesting because the MN bonds in these complexes are relatively weak in comparison with other latemetal MX bonds (halide, alkyl, hydrido, etc.) and thus exhibit unusual reactivities. 1 Stable amido complexes of nickel are limited to the (trialkylsily1) amido derivatives (PPh3) 2Ni {N (SiMe3) 2} and