Croatica chemica acta

GC-MS characterization of acetylated β-D-glucopyranosides: transglucosylation of volatile alcohols using almond β-glucosidase

I Jerković, J Mastelić

文献索引：Jerkovic, Igor; Mastelic, Josip Croatica Chemica Acta, 2004 , vol. 77, # 3 p. 529 - 535

被引用次数: 13

摘要

Sažetak β-D-Glucopyranosides of pentan-1-ol,(±)-pentan-2-ol, hexan-1-ol, octan-1-ol, benzyl alcohol, 2-phenylethanol,(±)-2-phenyl-propan-1-ol, 3-phenyl-propan-1-ol, geraniol and nerol were synthesized by transglucosylation of the respective alcohols with cellobiose using almond β-glucosidase. The reaction was carried out in acetonitrile with acetate buffer (vol. ratio 9: 1), with the yields 14.4–45.0%. Transglucosylation was not enantioselective. ...