Tetrahedron

Various oxidative reactions with novel ion-supported (diacetoxyiodo) benzenes

M Iinuma, K Moriyama, H Togo

文献索引：Iinuma, Masataka; Moriyama, Katsuhiko; Togo, Hideo Tetrahedron, 2013 , vol. 69, # 14 p. 2961 - 2970

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被引用次数: 21

摘要

The oxidation of secondary alcohols and primary alcohols with two novel ion-supported (diacetoxyiodo) benzenes (IS-DIBs) A and B in the presence of a catalytic amount of 2, 2, 6, 6-tetramethylpiperidine-1-oxyl radical (TEMPO) in dichloromethane at room temperature proceeded efficiently to provide the corresponding ketones and aldehydes, respectively, in good yields. The oxidative reaction of N, N-diisopropylbenzylamines with those IS-DIBs ...