The Journal of Organic Chemistry

The Chemistry of Methyl Vinyl Ketone. I. The Acetoethylation of Ketones

NC Ross, R Levine

文献索引：Ross,N.C.; Levine,R. Journal of Organic Chemistry, 1964 , vol. 29, p. 2341 - 2346

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被引用次数: 20

摘要

JIethyl isopropyl ketone did not undergo the 1Iichael condensation with illethyl vinyl ketone under the reactions used in the present study. While the acyclic ketones showed little or no (0-l, j., jyc) tendency to add to methyl vinyl ketone, the cyclic ketones, cyclopentanone, cyclohexanone, and 2-niethylcyclohexane, reacted readily to give fair to good yields of condensation products. Cyclopentanone, when converted to its anion, was acetoethylated ...