19559-06-9

19559-06-9 structure
19559-06-9 structure

Name trichlorotris(tetrahydrofuran)vanadium
Synonyms Vanadium(III) chloride-tetrahydrofuran complex (1:3),0.5M solution in methylene chloride,AcroSeal
VANADIUM(III) CHLORIDE-TETRAHYDROFURAN C OMPLEX (1:3),0.5M SOLN IN CH2CL2
Vanadium(III) chloride-tetrahydrofuran complex
Vanadium(III) chloride-tetrahydrofuran complex (1:3) solution
MFCD00145515
VANADIUM (III) CHLORIDE TETRAHYDROFURAN ADDUCT
[VCl3(tetrahydrofuran)3]
Vanadiumchloridetetrahydrofuranadductredxtl
trichlorotris(tetrahydrofuran)vanadium(III)
VANADIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX (1:3)
[VCl3(thf)3]
Density 1.312 g/mL at 25ºC
Boiling Point 40ºC
Melting Point 265ºC (dec.)(lit.)
Molecular Formula C4H8Cl3OV
Molecular Weight 229.40600
Flash Point 18 °F
Exact Mass 227.90800
PSA 9.23000
LogP 2.86530
Vapour Pressure 152mmHg at 25°C

Section 1: Product Identification
Chemical Name:Vanadium (III) chloride tetrahydrofuran adduct
CAS Registry Number:19559-06-9
Formula:VCl3(C4H8O)2-3
EINECS Number:none
Chemical Family:metal halide
Synonym:Vanadium trichloride tetrahydrofuran adduct

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound19559-06-9100%no datano data

Section 3: Hazards Identification
Corrosive to skin and eyes. May release toxic and corrosive fumes of hydrogen chloride and aqueous
Emergency Overview:
hydrochloric acid. Tetrahydrofuran can cause drowsiness and unconsciousness.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:Severe corrosive to the eyes. Exposure can lead to permanent eye damage.
Skin Contact:Corrosive to skin. Contact can lead to redness, pain, blistering, ulceration, and scar formation.
Inhalation of tetrahydrofuran vapor may cause coughing, nausea, dizziness, headache, drowsiness, and
Inhalation:
unconsciousness.
Ingestion:Ingestion of tetrahydrofuran or hydrogen chloride may cause gastrointestinal and respiratory irritation.
Inhalation of vapor induces drowsiness and may cause coughing, chest pains, difficulty in breathing, nausea,
Acute Health Affects:
dizziness, headache and unconsciousness. Hydrogen chloride can cause pulmonary edema.
Chronic Health Affects:In animal studies tetrahydrofuran acted as a tumorigen (liver), mutagen and reproductive effector.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus.
Hazardous Combustion andIf involved in a fire this material may emit toxic fumes of hydrogen chloride, carbon monoxide, carbon dioxide,
Decomposion Products:and organic fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid
Spill and Leak Procedures:
raising dust.

SECTION 7: Handling and Storage
Store solid in a tightly sealed container away from moisture. Handle in a fume hood under a dry atmosphere of
Handling and Storage:
air or nitrogen. Prolonged exposure to the atmosphere may degrade the product.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:red xtl.
Molecular Weight:157.3
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:pungent odor
Solubility in Water:reacts with water

SECTION 10: Stability and Reactivity
Stability:moisture sensitive (store cold)
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:Water, alcohols, oxidizing agents, oxygen and active metals
Decomposition Products:Vanadium oxychloride, hydrogen chloride, carbon dioxide, carbon monoxide, organic fumes.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Corrosive solids, N.O.S.
Hazard Class (CFR):8
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 1759
Shipping Name (IATA):Corrosive solid, N.O.S.
Hazard Class (IATA):8
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1759

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):See category code N770 for reporting.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger
Hazard Statements H228-H302 + H312 + H332-H314
Precautionary Statements P210-P280-P305 + P351 + P338-P310
Hazard Codes C: Corrosive;F: Flammable;
Risk Phrases 20/21/22-34-40-11
Safety Phrases 26-27-28-36/37/39-45-23-16
RIDADR UN 2925 4.1/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8