中文名 | 三氯化矾四氢呋喃络合物 |
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英文名 | trichlorotris(tetrahydrofuran)vanadium |
英文别名 |
Vanadium(III) chloride-tetrahydrofuran complex (1:3),0.5M solution in methylene chloride,AcroSeal
VANADIUM(III) CHLORIDE-TETRAHYDROFURAN C OMPLEX (1:3),0.5M SOLN IN CH2CL2 Vanadium(III) chloride-tetrahydrofuran complex Vanadium(III) chloride-tetrahydrofuran complex (1:3) solution MFCD00145515 VANADIUM (III) CHLORIDE TETRAHYDROFURAN ADDUCT [VCl3(tetrahydrofuran)3] Vanadiumchloridetetrahydrofuranadductredxtl trichlorotris(tetrahydrofuran)vanadium(III) VANADIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX (1:3) [VCl3(thf)3] |
密度 | 1.312 g/mL at 25ºC |
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沸点 | 40ºC |
熔点 | 265ºC (dec.)(lit.) |
分子式 | C4H8Cl3OV |
分子量 | 229.40600 |
闪点 | 18 °F |
精确质量 | 227.90800 |
PSA | 9.23000 |
LogP | 2.86530 |
蒸汽压 | 152mmHg at 25°C |
计算化学 | 1、 氢键供体数量:4 2、 氢键受体数量:7 3、 可旋转化学键数量:1 4、 互变异构体数量:9 5、 拓扑分子极性表面积(TPSA):141 6、 重原子数量:13 7、 表面电荷:0 8、 复杂度:117 9、 同位素原子数量:0 10、 确定原子立构中心数量:0 11、 不确定原子立构中心数量:0 12、 确定化学键立构中心数量:0 13、 不确定化学键立构中心数量:0 14、 共价键单元数量:2 |
更多 | 1. 性状:不确定 2. 密度(g/mL,25/4℃):1.312 3. 相对蒸汽密度(g/mL,空气=1):不确定 4. 熔点(ºC):265°C (dec.)(lit.) 5. 沸点(ºC,常压):不确定 6. 沸点(ºC, 5mm ):40 7. 折射率:不确定 8. 闪点(ºF):18 9. 比旋光度(º):不确定 10. 自燃点或引燃温度(ºC):不确定 11. 蒸气压(kPa,25ºC):不确定 12. 饱和蒸气压(kPa,60ºC):不确定 13. 燃烧热(KJ/mol):不确定 14. 临界温度(ºC):不确定 15. 临界压力(KPa):不确定 16. 油水(辛醇/水)分配系数的对数值:不确定 17. 爆炸上限(%,V/V):不确定 18. 爆炸下限(%,V/V):不确定 19. 溶解性:不确定 |
Section 1: Product Identification Chemical Name:Vanadium (III) chloride tetrahydrofuran adduct CAS Registry Number:19559-06-9 Formula:VCl3(C4H8O)2-3 EINECS Number:none Chemical Family:metal halide Synonym:Vanadium trichloride tetrahydrofuran adduct
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound19559-06-9100%no datano data Section 3: Hazards Identification Corrosive to skin and eyes. May release toxic and corrosive fumes of hydrogen chloride and aqueous Emergency Overview: hydrochloric acid. Tetrahydrofuran can cause drowsiness and unconsciousness. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Severe corrosive to the eyes. Exposure can lead to permanent eye damage. Skin Contact:Corrosive to skin. Contact can lead to redness, pain, blistering, ulceration, and scar formation. Inhalation of tetrahydrofuran vapor may cause coughing, nausea, dizziness, headache, drowsiness, and Inhalation: unconsciousness. Ingestion:Ingestion of tetrahydrofuran or hydrogen chloride may cause gastrointestinal and respiratory irritation. Inhalation of vapor induces drowsiness and may cause coughing, chest pains, difficulty in breathing, nausea, Acute Health Affects: dizziness, headache and unconsciousness. Hydrogen chloride can cause pulmonary edema. Chronic Health Affects:In animal studies tetrahydrofuran acted as a tumorigen (liver), mutagen and reproductive effector. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus. Hazardous Combustion andIf involved in a fire this material may emit toxic fumes of hydrogen chloride, carbon monoxide, carbon dioxide, Decomposion Products:and organic fumes. Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid Spill and Leak Procedures: raising dust. SECTION 7: Handling and Storage Store solid in a tightly sealed container away from moisture. Handle in a fume hood under a dry atmosphere of Handling and Storage: air or nitrogen. Prolonged exposure to the atmosphere may degrade the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:red xtl. Molecular Weight:157.3 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:pungent odor Solubility in Water:reacts with water SECTION 10: Stability and Reactivity Stability:moisture sensitive (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:contact with moisture Incompatibility:Water, alcohols, oxidizing agents, oxygen and active metals Decomposition Products:Vanadium oxychloride, hydrogen chloride, carbon dioxide, carbon monoxide, organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Corrosive solids, N.O.S. Hazard Class (CFR):8 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1759 Shipping Name (IATA):Corrosive solid, N.O.S. Hazard Class (IATA):8 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1759 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):See category code N770 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
符号 |
GHS02, GHS05, GHS07 |
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信号词 | Danger |
危害声明 | H228-H302 + H312 + H332-H314 |
警示性声明 | P210-P280-P305 + P351 + P338-P310 |
危害码 (欧洲) | C: Corrosive;F: Flammable; |
风险声明 (欧洲) | 20/21/22-34-40-11 |
安全声明 (欧洲) | 26-27-28-36/37/39-45-23-16 |
危险品运输编码 | UN 2925 4.1/PG 2 |
WGK德国 | 3 |
包装等级 | III |
危险类别 | 8 |
上游产品 0 | |
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下游产品 5 | |