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1,1-Bis(t-butylperoxy)-3,3,5-trimethylcyclohexane

Names

[ CAS No. ]:
6731-36-8

[ Name ]:
1,1-Bis(t-butylperoxy)-3,3,5-trimethylcyclohexane

[Synonym ]:
1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane
luperco231g
luperco231xl
MFCD00084801
perhexa3m
lupersol231
EINECS 229-782-3
1,1-di-tert.-butyl peroxy-3,3,5-trimethyl cyclohexane
trigonox 29
1,1,5-Trimethyl-3,3-bis[(2-methyl-2-propanyl)peroxy]cyclohexane
TMCH
LUPEROX 231
VAROX 231
perhexa3m40

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
312.2±12.0 °C at 760 mmHg

[ Melting Point ]:
-20 °C

[ Molecular Formula ]:
C17H34O4

[ Molecular Weight ]:
302.449

[ Flash Point ]:
108.7±19.4 °C

[ Exact Mass ]:
302.245697

[ PSA ]:
36.92000

[ LogP ]:
6.91

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.453

[ Storage condition ]:
Refrigerator (+4°C)

[ Water Solubility ]:
immiscible

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SD8600000
CHEMICAL NAME :
Peroxide, (3,3,5-trimethylcyclohexylidene)bis((1,1-dimethylethy l)
CAS REGISTRY NUMBER :
6731-36-8
LAST UPDATED :
199707
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C17-H34-O4
MOLECULAR WEIGHT :
302.51

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
12918 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ESKHA5 Eisei Shikenjo Hokoku. Bulletin of the Institute of Hygienic Sciences. (Kokuritsu Eisei Shikenjo Kagaku, 18-1 Bushitsu Johobu, Setagaya-ku, Tokyo 158, Japan) V.1- 1886- Volume(issue)/page/year: (110),42,1992 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
109 gm/kg/13W-C
TOXIC EFFECTS :
Liver - changes in liver weight Blood - pigmented or nucleated red blood cells Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
ESKHA5 Eisei Shikenjo Hokoku. Bulletin of the Institute of Hygienic Sciences. (Kokuritsu Eisei Shikenjo Kagaku, 18-1 Bushitsu Johobu, Setagaya-ku, Tokyo 158, Japan) V.1- 1886- Volume(issue)/page/year: (110),42,1992

Safety Information

[ Symbol ]:

GHS01, GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H241-H413

[ Precautionary Statements ]:
P220-P261-P280-P305 + P351 + P338-P410 + P412

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
O:Oxidizingagent;

[ Risk Phrases ]:
R7

[ Safety Phrases ]:
S7-S17-S36/37/39-S3/7-S28B-S26-S14A-S14-S47-S61-S45-S53

[ RIDADR ]:
UN 3110 5.2

[ WGK Germany ]:
3

[ RTECS ]:
SD8600000

[ Packaging Group ]:
II

[ Hazard Class ]:
5.2

[ HS Code ]:
2909600000

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2909600000

[ Summary ]:
2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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Eisei Shikenjo Hokoku. (110) , 42-8, (1992)

A 13-week subchronic toxicity study of 1,1-bis(t-butylperoxy)3,3,5-trimethyl cyclohexane (TMCH) was performed in male and female B6C3F1 mice by feeding a CRF-1 powder diet containing 0, 0.5, 1.0, 2.0 ...


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