(1,1,2,2-TETRAFLUOROETHOXY)BENZENE

Names

[ Name ]:
(1,1,2,2-TETRAFLUOROETHOXY)BENZENE

[Synonym ]:
Acetophenone dimethyl acetal
Benzene,(1,1-dimethoxyethyl)
MFCD00075617
methyl phenyl ketone dimethyl acetal
acetophenone dimethyl ketal
AC1Q55VS
2,2-dimethoxy-1-phenylethane
EINECS 224-334-3
1-phenyl-1,1-dimethoxyethane
AC1L2UAB
ACMC-20aprm
(1,1-dimethoxyethyl) benzene
1-phenyl-2,2'-dimethoxyethane

Chemical & Physical Properties

[ Density]:
1.008 g/mL at 25ºC(lit.)

[ Boiling Point ]:
95-98ºC12 mm Hg(lit.)

[ Melting Point ]:
58-60 °C

[ Molecular Formula ]:
C₁₀H₁₄O₂

[ Molecular Weight ]:
166.21700

[ Flash Point ]:
152 °F

[ Exact Mass ]:
166.09900

[ PSA ]:
18.46000

[ LogP ]:
2.15210

[ Appearance of Characters ]:
Liquid，Colorless

[ Index of Refraction ]:
n20/D 1.49(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2911000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2911000000

[ Summary ]:
2911000000 acetals and hemiacetals, whether or not with other oxygen function, and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

A simple and efficient chemoselective method for the catalytic deprotection of acetals and ketals using bismuth triflate.

J. Org. Chem. 67(3) , 1027-30, (2002)

Bismuth triflate is a highly efficient catalyst (0.1-1 mol %) for the deprotection of acetals and ketals. The procedure is very facile and selective for acetals derived from ketones and conjugated ald...