CHLORANIL
Names
[ CAS No. ]:
118-75-2
[ Name ]:
CHLORANIL
[Synonym ]:
2,3,5,6-tetrachloro-2,5-cyclohexadiene-1,4-dione
2,3,5,6-tetrachloro-p-benzoquinone
Reranil
p-Chloranil
2-Propanol, aluminum salt (3:1)
Khloranil
2,3,5,6-Tetrachlorocyclohexa-2,5-diene-1,4-dione
Aluminium tri(2-propanolate)
tetrachloro-p-benzoquinone
Coversan
2,3,5,6-Tetrachloro-1,4-benzoquinone,p-Chloranil,Chloranil
Aluminum isopropoxide
Psorisan
CHLORANIL
Spergon
2,3,5,6-Tetrachloro-1,4-benzoquinone
2,5-Cyclohexadiene-1,4-dione, 2,3,5,6-tetrachloro-
MFCD00001594
Tetrachloro-1,4-benzoquinone
EINECS 204-274-4
tetrachloro-1-4-benzoquinone
Aluminum tripropan-2-olate
Chemical & Physical Properties
[ Density]:
1.8±0.1 g/cm3
[ Boiling Point ]:
269.5±40.0 °C at 760 mmHg
[ Melting Point ]:
295-296 °C (dec.)
[ Molecular Formula ]:
C6Cl4O2
[ Molecular Weight ]:
245.88
[ Flash Point ]:
111.7±27.9 °C
[ Exact Mass ]:
204.130615
[ PSA ]:
34.14000
[ LogP ]:
1.39
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.595
[ Water Solubility ]:
insoluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DK6825000
- CHEMICAL NAME :
- p-Benzoquinone, 2,3,5,6-tetrachloro-
- CAS REGISTRY NUMBER :
- 118-75-2
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 14
- MOLECULAR FORMULA :
- C6-Cl4-O2
- MOLECULAR WEIGHT :
- 245.86
- WISWESSER LINE NOTATION :
- L6V DVJ BG CG EG FG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 4 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2485 mg/m3/4H
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Nutritional and Gross Metabolic - weight loss or decreased weight gain
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 8450 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 15 gm/kg/8D-I
- TOXIC EFFECTS :
- Behavioral - food intake (animal) Blood - change in clotting factors Blood - changes in leukocyte (WBC) count
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 66956 mg/kg/22W-C
- TOXIC EFFECTS :
- Liver - fatty liver degeneration Nutritional and Gross Metabolic - weight loss or decreased weight gain
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 49915 mg/kg/67D-C
- TOXIC EFFECTS :
- Related to Chronic Data - death
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 71 gm/kg/78W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Liver - tumors
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- DOSE/DURATION :
- 1100 nmol/plate
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 347,37,1995 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84201 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 41 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84201 No. of Facilities: 125 (estimated) No. of Industries: 3 No. of Occupations: 8 No. of Employees: 2098 (estimated) No. of Female Employees: 761 (estimated)
Safety Information
[ Symbol ]:
GHS07, GHS09
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H410
[ Precautionary Statements ]:
P273-P305 + P351 + P338-P501
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn:Harmful
[ Risk Phrases ]:
R20;R36/38;R50/53
[ Safety Phrases ]:
S37-S60-S61-S22
[ RIDADR ]:
UN 3077 9/PG 3
[ WGK Germany ]:
2
[ RTECS ]:
DK6825000
[ Packaging Group ]:
III
[ Hazard Class ]:
9
[ HS Code ]:
29147090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2914700013
[ Summary ]:
HS:2914700013 2,3,5,6-tetrachlorocyclohexa-2,5-diene-1,4-dione VAT:17.0% Tax rebate rate:0.0% Supervision conditions:S MFN tariff:5.5% General tariff:30.0%
Articles
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The phytochemical profile and antioxidant activities of unprocessed and extruded milled fractions of black rice were investigated. Extrusion increased the free phenolics, anthocyanins and oxygen radic...
Quantitative structure-activity relationship and complex network approach to monoamine oxidase A and B inhibitors.J. Med. Chem. 51 , 6740-51, (2008)
The work provides a new model for the prediction of the MAO-A and -B inhibitor activity by the use of combined complex networks and QSAR methodologies. On the basis of the obtained model, we prepared ...