1-Bromo-3-(trifluoromethoxy)benzene
Names
[ CAS No. ]:
2252-44-0
[ Name ]:
1-Bromo-3-(trifluoromethoxy)benzene
[Synonym ]:
3-Bromo-α,α,α-trifluoroanisole
3-Bromo-1-(trifluoromethoxy)benzene
1-Bromo-3-(trifluoromethoxy)benzene
3-(Trifluoromethoxy)bromobenzene
3-Bromo(trifluoromethoxy)benzene
m-bromophenyl trifluoromethyl ether
FXFFOR CE
MFCD00040943
M-BROMO(TRIFLUOROMETHOXY)BENZENE
Benzene, 1-bromo-3-(trifluoromethoxy)-
3-Bromophenyl trifluoromethyl ether
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
161.9±35.0 °C at 760 mmHg
[ Molecular Formula ]:
C7H4BrF3O
[ Molecular Weight ]:
241.005
[ Flash Point ]:
62.8±0.0 °C
[ Exact Mass ]:
239.939758
[ PSA ]:
9.23000
[ LogP ]:
4.06
[ Vapour Pressure ]:
2.9±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.475
MSDS
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
[ Hazard Codes ]:
Xi:Irritant
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S37/39-S26
[ WGK Germany ]:
3
[ HS Code ]:
2909309090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2909309090
[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
European J. Org. Chem. 21 , 3991-97, (2001)
The use of arynes in organic synthesis. Pellissier H and Santelli M.
Tetrahedron 59(6) , 701-30, (2003)
A new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep and its application in asymmetric hydrogenation. Zhang D-Y, et al.
Tetrahedron Lett. 53(20) , 2556-59, (2012)