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1,2,3-三氯丙烯

1,2,3-三氯丙烯用途

用作除草剂燕麦敌的中间体。

　主要用作农药除草剂燕麦畏、燕麦敌1号的中间体，也是制造特种塑料的原料。

1,2,3-三氯丙烯名称

[ CAS 号 ]:
96-19-5

[ 中文名 ]:
1,2,3-三氯丙烯

[ 英文名 ]:
1,2,3-TRICHLOROPROPENE

[英文别名 ]:

1,2,3-Trichlor-propen
EINECS 202-487-7
1,2,3-trichloro-propen
(Z),(E)-1,2,3-trichloro-1-propene
1,2,3-Trichlor-propen-(1)
1,2,3-trichroro-1-propene
MFCD00018931
1,2,3-Trichloro-1-propene
1,2,3-trichloropropylene
Wln: G1ygu1g

1,2,3-三氯丙烯物理化学性质

[ 密度 ]:
1,43 g/cm3

[ 沸点 ]:
145°C

[ 分子式 ]:
C₃H₃Cl₃

[ 分子量 ]:
145.41500

[ 闪点 ]:
82°C

[ 精确质量 ]:
143.93000

[ LogP ]:
2.54420

[ 外观性状 ]:
液体;Colorless to Almost colorless clear liquid

[ 折射率 ]:
1.487

[ 储存条件 ]:
室温

1,2,3-三氯丙烯MSDS

详细MSDS(安全技术说明书)

1,2,3-三氯丙烯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UD2450000

CHEMICAL NAME :: Propene, 1,2,3-trichloro-

CAS REGISTRY NUMBER :: 96-19-5

LAST UPDATED :: 199807

DATA ITEMS CITED :: 11

MOLECULAR FORMULA :: C3-H3-Cl3

MOLECULAR WEIGHT :: 145.41

WISWESSER LINE NOTATION :: G1YGU1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 616 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 640 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 36 ppm/6H/4W-IW-C

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Vascular - regional or general arteriolar or venous dilation Lungs, Thorax, or Respiration - dyspnea

MUTATION DATA

TYPE OF TEST :: DNA inhibition

TEST SYSTEM :: Human HeLa cell

DOSE/DURATION :: 1700 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 92,427,1982

1,2,3-三氯丙烯安全信息

[ 风险声明 (欧洲) ]:
20/21/22-36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37/39

[ 危险品运输编码 ]:
2810

[ RTECS号 ]:
UD2450000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2903299090

1,2,3-三氯丙烯上下游产品

1,2,3-三氯丙烯上游产品

1,2,3-三氯丙烯下游产品

1,2,3-三氯丙烯制备

其制备方法是将四氯丙烷及乙醇加到反应釜中，搅拌加热至回流，在1 h内分批加入氢氧化钾，加毕回流2 h，冷却、过滤，滤液水洗2次，水层用二氯乙烷萃取，并与油层合并，脱溶，减压蒸馏，收集74～91℃/13.3 kPa馏分即为成品。

1,2,3-三氯丙烯海关

[ 海关编码 ]: 2903299090

[ 中文概述 ]:
HS: 2903299090. 其他无环烃的不饱和氯化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%