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(S)-(+)-对甲苯磺酸缩水甘油酯

(S)-(+)-对甲苯磺酸缩水甘油酯用途

【用途一】
用于合成多种手性医药中间体

(S)-(+)-对甲苯磺酸缩水甘油酯名称

[ CAS 号 ]:
70987-78-9

[ 中文名 ]:
(2S)-(+)-缩水甘油基对甲苯磺酸酯

[ 英文名 ]:
(S)-Glycidyl tosylate

[中文别名 ]:

[英文别名 ]:

(2S)-2-Oxiranylmethyl 4-methylbenzenesulfonate
T3OTJ B1OSWR D1 &&S Form
EINECS 417-210-7
[(2S)-oxiran-2-yl]methyl 4-methylbenzenesulfonate
(2S)-Glycidyl tosylate
2-Oxiranemethanol, 4-methylbenzenesulfonate, (2S)-
MFCD00064489
(2S)-Oxiran-2-ylmethyl-4-methylbenzolsulfonat
(2S)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
(S)-Glycidyl tosylate

(S)-(+)-对甲苯磺酸缩水甘油酯物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
370.5±15.0 °C at 760 mmHg

[ 熔点 ]:
45-48ºC

[ 分子式 ]:
C₁₀H₁₂O₄S

[ 分子量 ]:
228.265

[ 闪点 ]:
177.9±20.4 °C

[ 精确质量 ]:
228.045624

[ PSA ]:
64.28000

[ LogP ]:
1.35

[ 外观性状 ]:
白色粉末

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.550

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)

(S)-(+)-对甲苯磺酸缩水甘油酯MSDS

(S)-(+)-对甲苯磺酸缩水甘油酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RR0510050

CHEMICAL NAME :: Oxiranemethanol, 4-methylbenzenesulfonate, (S)-

CAS REGISTRY NUMBER :: 70987-78-9

BEILSTEIN REFERENCE NO. :: 3592143

LAST UPDATED :: 199612

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C10-H12-O4-S

MOLECULAR WEIGHT :: 228.28

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Mutation test systems - not otherwise specified

TYPE OF TEST :: Cytogenetic analysis

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993

(S)-(+)-对甲苯磺酸缩水甘油酯安全信息

[ 符号 ]:

GHS05, GHS07, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H317-H318-H341-H350-H411

[ 警示性声明 ]:
P201-P273-P280-P305 + P351 + P338-P308 + P313

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic

[ 风险声明 (欧洲) ]:
R41;R43;R45;R51/53

[ 安全声明 (欧洲) ]:
S45-S53-S61

[ 危险品运输编码 ]:
UN 3077

[ WGK德国 ]:
3

[ RTECS号 ]:
RR0510050

[ 危险类别 ]:
9.0

[ 海关编码 ]:
29109000

(S)-(+)-对甲苯磺酸缩水甘油酯合成路线

(S)-(+)-对甲苯磺酸缩水甘油酯上下游产品

(S)-(+)-对甲苯磺酸缩水甘油酯上游产品

(S)-(+)-对甲苯磺酸缩水甘油酯下游产品

(S)-(+)-对甲苯磺酸缩水甘油酯海关

[ 海关编码 ]: 2910900090

[ 中文概述 ]:
2910900090. 三节环环氧化物，环氧醇（酚，醚），包括其卤化，磺化，硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

(S)-(+)-对甲苯磺酸缩水甘油酯文献

Henry, N. et al.

Tetrahedron Lett. 45 , 1465, (2004)

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