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2-甲氧基苯甲酸甲酯

2-甲氧基苯甲酸甲酯名称

[ CAS 号 ]:
606-45-1

[ 中文名 ]:
2-甲氧基苯甲酸甲酯

[ 英文名 ]:
Methyl 2-methoxybenzoate

[中文别名 ]:

[英文别名 ]:

Methyol o-methoxybenzoate
Methyl o-anisate
dimethyl salicylate
methyl methoxybenzoate
Methyl o-methoxybenzoate
methoxy-benzoic acid methyl ester
2-Methoxybenzoic Acid Methyl Ester
BENZOIC ACID,2-METHOXY-,METHYL ESTER
methyl monomethoxybenzoate
o-Methoxybenzoic acid methyl ester

2-甲氧基苯甲酸甲酯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
245.0±0.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₁₀O₃

[ 分子量 ]:
166.174

[ 闪点 ]:
93.8±14.4 °C

[ 精确质量 ]:
166.062988

[ PSA ]:
35.53000

[ LogP ]:
2.04

[ 外观性状 ]:
无色或淡黄色液体带有一种温暖的,草本的,植物,辛辣的气味

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.503

[ 储存条件 ]:
室温，干燥

2-甲氧基苯甲酸甲酯MSDS

2-甲氧基苯甲酸甲酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DH3549000

CHEMICAL NAME :: Benzoic acid, 2-methoxy-, methyl ester

CAS REGISTRY NUMBER :: 606-45-1

BEILSTEIN REFERENCE NO. :: 2207356

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C9-H10-O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 26,385,1988

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 26,385,1988

2-甲氧基苯甲酸甲酯安全信息

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
DH3549000

[ 海关编码 ]:
29189090

2-甲氧基苯甲酸甲酯合成路线

2-甲氧基苯甲酸甲酯上下游产品

2-甲氧基苯甲酸甲酯上游产品

2-甲氧基苯甲酸甲酯下游产品

2-甲氧基苯甲酸甲酯海关

[ 海关编码 ]: 2918990090

[ 中文概述 ]:
2918990090. 其他含其他附加含氧基羧酸（包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

2-甲氧基苯甲酸甲酯文献

Cross dehydrogenative arylation (CDA) of a benzylic C-H bond with arenes by iron catalysis.

Angew. Chem. Int. Ed. Engl. 48(21) , 3817-20, (2009)

Hooking up: FeCl(2) catalyzes the efficient cross dehydrogenative arylation of substrates having benzylic C-H bonds (see scheme). High regioselectivity was observed during the cross-coupling between c...

Synthesis of (+/-)-vibralactone.

Org. Lett. 10(7) , 1401-4, (2008)

Reductive alkylation of methyl 2-methoxybenzoate with prenyl bromide and hydrolysis afforded methyl 6-oxo-1-prenyl-2-cyclohexenecarboxylate. Reduction of the ketone, hydrolysis, iodolactonization, ozo...

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