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2-(三甲硅烷氧基)-1,3-环己二烯

2-(三甲硅烷氧基)-1,3-环己二烯名称

[ CAS 号 ]:
54781-19-0

[ 中文名 ]:
1-(三甲基硅氧基)-3,4-二氢苯

[ 英文名 ]:
(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane

[中文别名 ]:

[英文别名 ]:

(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane
(Cyclohexa-1,5-dien-1-yloxy)(trimethyl)silane
1,3-Cyclohexadiene, 2-[(trimethylsilyl)oxy]-
MFCD00274202
cyclohexa-1,5-dien-1-yloxy(trimethyl)silane

2-(三甲硅烷氧基)-1,3-环己二烯物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
187.6±8.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₁₆OSi

[ 分子量 ]:
168.308

[ 闪点 ]:
58.7±8.7 °C

[ 精确质量 ]:
168.097046

[ PSA ]:
9.23000

[ LogP ]:
3.44

[ 外观性状 ]:
液体;Colorless to Almost colorless clear liquid

[ 蒸汽压 ]:
0.9±0.3 mmHg at 25°C

[ 折射率 ]:
1.465

[ 储存条件 ]:
0-10°C;存放于惰性气体之中;避免湿气 (分解),加热

2-(三甲硅烷氧基)-1,3-环己二烯MSDS

2-(三甲硅烷氧基)-1,3-环己二烯安全信息

[ 符号 ]:

GHS02

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F+

[ 风险声明 (欧洲) ]:
10

[ 安全声明 (欧洲) ]:
16

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ 海关编码 ]:
2931900090

2-(三甲硅烷氧基)-1,3-环己二烯合成路线

2-(三甲硅烷氧基)-1,3-环己二烯上下游产品

2-(三甲硅烷氧基)-1,3-环己二烯上游产品

2-(三甲硅烷氧基)-1,3-环己二烯下游产品

2-(三甲硅烷氧基)-1,3-环己二烯海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

2-(三甲硅烷氧基)-1,3-环己二烯文献

2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction.

J. Org. Chem. 68(21) , 8256-7, (2003)

The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield...

High-Temperature Diels-Alder Reactions: Transfer from Batch to Continuous Mode. Abele S, et al.

Org. Process Res. Dev. 16(5) , 1114-1120, (2011)

Design and Scale-Up of Diels-Alder Reactions for the Practical Synthesis of 5-Phenylbicyclo [2.2. 2] oct-5-en-2-one. Funel JA, et al.

Org. Process Res. Dev. 15(6) , 1420-1427, (2011)

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