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1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯名称

[ CAS 号 ]:
31469-15-5

[ 中文名 ]:
1-甲氧基-1-(三甲基甲硅氧基)-2-甲基-1-丙烯

[ 英文名 ]:
1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene

[中文别名 ]:

[英文别名 ]:

MTDA
2-methyl-1-methoxy-1-trimethylsilyloxypropene
methoxy-1-trimethylsilyloxy-2,2-dimethylethylene
1-Methoxy-1-trimethylsilyloxy-2-methyl-1-propene
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene
1-methoxy-2-methyl-1-trimethylsiloxy-1-propene
MFCD00010232
1-methoxy-1-trimethylsilyloxy-2-methylpropene
methyl trimethylsilyl dimethylketene acetal
DiMethylketene Methyl TriMethylsilyl Acetal

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
137.4±0.0 °C at 760 mmHg

[ 分子式 ]:
C₈H₁₈O₂Si

[ 分子量 ]:
174.313

[ 闪点 ]:
14.4±0.0 °C

[ 精确质量 ]:
174.107605

[ PSA ]:
18.46000

[ LogP ]:
3.27

[ 外观性状 ]:
液体;Colorless to Almost colorless clear liquid

[ 蒸汽压 ]:
8.8±0.2 mmHg at 25°C

[ 折射率 ]:
1.419

[ 储存条件 ]:
2-8°C

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯MSDS

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S16-S26-S36

[ 危险品运输编码 ]:
UN 3271 3/PG 3

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2931900090

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯合成路线

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯上下游产品

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯上游产品

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯下游产品

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

1-甲氧基-2-甲基-1-(三甲基硅氧基)丙烯文献

Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.

J. Am. Chem. Soc. 129 , 6756, (2007)

Mannich-type reaction of ketene silyl acetals with aldimines proceeded catalytically by means of a phosphoric acid diester, derived from (R)-BINOL, as a chiral Brønsted acid to afford beta-amino ester...

Aldrichimica Acta 17 , 41, (1984)

Polymer J. Tokyo 26 , 169, (1994)

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