<生产厂家价格>

9-硼双环[3.3.1]壬烷

9-硼双环[3.3.1]壬烷用途

广泛的硼氢化试剂，其区域选择性和立体选择性都优于其它硼氢化试剂。如高选择地与端基双键加成而内双键无影响。使烯还原成醇或成醛(酮)等;与炔反应成醛(酮);也能还原酸、醋、酸氯、叔酸胺，优先还原不饱和醛酮中的拨基等等，

9-硼双环[3.3.1]壬烷名称

[ CAS 号 ]:
280-64-8

[ 中文名 ]:
9-硼双环[3.3.1]壬烷

[ 英文名 ]:
9-Borabicyclo[3.3.1]nonane

[中文别名 ]:

9-硼二环[3.3.1]壬烷

[英文别名 ]:

9-borabicyclononane
9-Borabicyclo[3.3.1]nonane solution
9-Borabicyclo(3.3.1)nonane
9-borabicyclo[3,3,1]nonane
EINECS 206-000-9
9-Borabicyclo[3.3.1]nonane
9-Borabicyclo[3.3.1]nonane monomer
9-BBN-dimer
MFCD00074742
Borabicyclononane

9-硼双环[3.3.1]壬烷物理化学性质

[ 密度 ]:
0.894 g/mL at 25 °C

[ 沸点 ]:
179.3±23.0 °C at 760 mmHg

[ 熔点 ]:
150 - 152ºC

[ 分子式 ]:
C₈H₁₅B

[ 分子量 ]:
122.016

[ 闪点 ]:
62.3±22.6 °C

[ 精确质量 ]:
122.126678

[ LogP ]:
2.36770

[ 外观性状 ]:
白色固体

[ 蒸汽压 ]:
1.3±0.3 mmHg at 25°C

[ 储存条件 ]:
Flammables area

[ 水溶解性 ]:
起反应

9-硼双环[3.3.1]壬烷MSDS

9-硼双环[3.3.1]壬烷安全信息

[ 符号 ]:

GHS02, GHS07, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H260-H302-H319-H335-H351

[ 补充危害声明 ]:
May form explosive peroxides.

[ 警示性声明 ]:
P210-P231 + P232-P280-P370 + P378-P402 + P404-P403 + P235

[ 危害码 (欧洲) ]:
F:Flammable;Xi:Irritant;

[ 风险声明 (欧洲) ]:
R11;R14/15;R36/37/38

[ 安全声明 (欧洲) ]:
16-26-36/37/39-45-43-33-62-61-36/37-29-7/8-37/39

[ 危险品运输编码 ]:
UN 3399 4.3/PG 1

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
4.1

[ 海关编码 ]:
2902199090

9-硼双环[3.3.1]壬烷合成路线

9-硼双环[3.3.1]壬烷上下游产品

9-硼双环[3.3.1]壬烷上游产品

9-硼双环[3.3.1]壬烷下游产品

9-硼双环[3.3.1]壬烷制备

注意!首次打开甲硼烷溶液瓶塞时，要在防护屏后面进行。在氮气存在下，在装有回流冷凝器、恒压滴液漏斗、电磁搅拌器和硅酮橡皮帽的2升三颈烧瓶中，加入800毫升1.0摩尔/升的(0.8摩尔)甲硼烷四氢吠喃溶,并置于冰浴中冷却。在滴液漏斗中将86.5克0.8摩尔)1，5一环辛二烯用四氢映喃稀释成200毫升，然后在激烈搅拌下于20一30分钟内将其滴加入三颈瓶中。加热回流1小时，冷却，即得有少量9一BBN结晶析出的饱
和溶液，其浓度为0.7878摩尔/升。置于冰浴中冷却，让其结晶完全。在氮气中吸滤，用干燥戊烷洗涤，收率65%(若以四氢肤喃溶液汁，近理论产率)。

9-硼双环[3.3.1]壬烷海关

[ 海关编码 ]: 2902199090

[ 中文概述 ]:
2902199090 其他环烷烃、环烯烃及环萜烯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:2.0%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量

[ Summary ]:
2902199090 other cyclanes, cyclenes and cyclotherpenes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

9-硼双环[3.3.1]壬烷文献

Spectroscopic and microscopic investigation of gold nanoparticle formation: ligand and temperature effects on rate and particle size.

J. Am. Chem. Soc. 133(21) , 8179-90, (2011)

We report a spectroscopic and microscopic investigation of the synthesis of gold nanoparticles (AuNPs) with average sizes of less than 5 nm. The slow reduction and AuNP formation processes that occur ...

Synthesis of aryl/alkyl building blocks for dendrimer and hyperbranched polymer synthesis.

Org. Lett. 6 , 667-669, (2004)

Several useful aryl/alkyl building blocks for dendrimer and hyperbranched polymer synthesis were prepared by Suzuki-Miyaura cross-coupling reactions and iododesilylation reactions. The iododesilylatio...

Multicomponent Mannich reactions with boron enolates derived from diazo esters and 9-BBN.

Org. Lett. 13 , 2510, (2011)

Diazo esters, arylboranes, and carbamoyl imines undergo a 3-component Mannich condensation reaction. Catalyzed by Cu(II) salts, the reaction affords the corresponding isocyanate Mannich product: one t...

更多文献