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L-(+)-酒石酸二异丙酯

L-(+)-酒石酸二异丙酯用途

【用途一】
用于有机合成。制备手性化合物。通过对映选择环氧化作用，用作外消旋烯丙基醇类的动力拆分。

L-(+)-酒石酸二异丙酯名称

[ CAS 号 ]:
2217-15-4

[ 中文名 ]:
L-(+)-酒石酸二异丙酯

[ 英文名 ]:
(+)-Diisopropyl L-tartrate

[中文别名 ]:

[英文别名 ]:

L-(+)-Tartaric acid diisopropyl ester
Diisoprropyl-L-tartrate
(2S,3S)-(-)-Diisopropyl 2,3-dihydroxysuccinate
D-(−)-Tartaric acid diisopropyl ester
EINECS 218-709-0
Diisopropyl (2S,3S)-2,3-dihydroxysuccinate
(+)-Diisopropyl L-tartrate
Diisopropyl L-(+)-Tartrate
(a")-Diisopropyl-D-tartrate
L-DIPT

L-(+)-酒石酸二异丙酯物理化学性质

[ 密度 ]:
1.114

[ 沸点 ]:
275 ºC

[ 分子式 ]:
C₁₀H₁₈O₆

[ 分子量 ]:
234.246

[ 闪点 ]:
110 ºC

[ 精确质量 ]:
234.110336

[ PSA ]:
93.06000

[ LogP ]:
0.41

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 折射率 ]:
1.468

[ 储存条件 ]:
室温，干燥

L-(+)-酒石酸二异丙酯MSDS

L-(+)-酒石酸二异丙酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WW8100000

CHEMICAL NAME :: Tartaric acid, diisopropyl ester

CAS REGISTRY NUMBER :: 2217-15-4

BEILSTEIN REFERENCE NO. :: 1727863

LAST UPDATED :: 199612

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C10-H18-O6

MOLECULAR WEIGHT :: 234.28

WISWESSER LINE NOTATION :: 1Y1&OVYQYQVOY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 6 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 93,26,1948

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 6300 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 93,26,1948

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >10 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 93,26,1948

L-(+)-酒石酸二异丙酯安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
WW8100000

[ 海关编码 ]:
29181300

L-(+)-酒石酸二异丙酯合成路线

L-(+)-酒石酸二异丙酯上下游产品

L-(+)-酒石酸二异丙酯上游产品

L-(+)-酒石酸二异丙酯下游产品

L-(+)-酒石酸二异丙酯海关

[ 海关编码 ]: 2918130000

[ 中文概述 ]:
2918130000 酒石酸盐及酒石酸酯. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2918130000 salts and esters of tartaric acid。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

L-(+)-酒石酸二异丙酯文献

J. Org. Chem. 59 , 1444, (1994)

J. Am. Chem. Soc. 115 , 12208, (1993)

Aldrichimica Acta 18 , 53, (1985)

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