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四氯化铂

四氯化铂用途

【用途一】
在容量分析中，用以测定钾、铯、钌、铵、铊、生物碱等，也用作催化剂
【用途二】
用于电镀。用作催化剂和分析试剂。也用于半导体生产中的外延、扩散工序。

四氯化铂名称

[ CAS 号 ]:
13454-96-1

[ 中文名 ]:
四氯化铂

[ 英文名 ]:
platinum tetrachloride

[中文别名 ]:

[英文别名 ]:

Platinum (IV) chloride
Platinum(4+) tetrachloride
PLATINUM CHLORIDE
MFCD00011182
(SP-4-1)-Platinumchloride
Tétrachlorure de Platine (4+)
PLATINIC CHLORIDE
Platinum(IV) chloride
platinum (IV)-chloride
tetrachloroplatinum

四氯化铂物理化学性质

[ 密度 ]:
4.303 g/mL at 25 °C(lit.)

[ 熔点 ]:
370 °C (dec.)(lit.)

[ 分子式 ]:
Cl₄Pt

[ 分子量 ]:
336.896

[ 精确质量 ]:
334.840210

[ LogP ]:
2.75550

[ 外观性状 ]:
结晶固体

[ 储存条件 ]:
室温，干燥，密封

[ 水溶解性 ]:
587 g/L (25 ºC)

四氯化铂MSDS

四氯化铂毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TP2275500

CHEMICAL NAME :: Platinum (IV) chloride

CAS REGISTRY NUMBER :: 13454-96-1

LAST UPDATED :: 199712

DATA ITEMS CITED :: 33

MOLECULAR FORMULA :: Cl4-Pt

MOLECULAR WEIGHT :: 336.89

WISWESSER LINE NOTATION :: .PT..G4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 276 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intratesticular

DOSE :: 26951 ug/kg

SEX/DURATION :: male 1 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Subcutaneous

DOSE :: 26951 ug/kg

SEX/DURATION :: male 1 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct

TYPE OF TEST :: Sex chromosome loss and nondisjunction

TYPE OF TEST :: DNA inhibition

MUTATION DATA

TYPE OF TEST :: Mutation in mammalian somatic cells

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 21 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 151,293,1985 *** REVIEWS *** ACGIH TLV-TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,213,1971 OSHA PEL (Gen Indu):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.002 mg(Pt)/m3 (dust) JAN 1993 OEL-AUSTRALIA:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-BELGIUM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-DENMARK:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-FINLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-GERMANY:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-HUNGARY:STEL 0.002 mg(Pt)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

四氯化铂安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H314-H317

[ 警示性声明 ]:
P280-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R22;R34;R42/43

[ 安全声明 (欧洲) ]:
S26-S27-S36/37/39-S45-S24-S22

[ 危险品运输编码 ]:
UN 2923 8/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
TP2275500

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2843900020

四氯化铂合成路线

四氯化铂上下游产品

四氯化铂上游产品

四氯化铂下游产品

四氯化铂制备

三、生产方法：由氯铂酸置于硬质玻璃管中的舟中，缓慢地将温度由 60℃ 升至 150℃ ，使水分完全挥发。在2h内继续升温至275～300℃，保温半小时，然后降温至 150℃ 。取出产品迅速粉碎后，重新置于舟中，在氯气流中加热至 275℃ 。保温半小时，趁热将产物投入密封瓶中制得。

四氯化铂海关

[ 海关编码 ]: 2843900020

四氯化铂文献

Complex anion inclusion compounds: flexible anion-exchange materials.

Chem. Commun. (Camb.) 49(3) , 249-51, (2013)

Copper chloropyrophosphate frameworks have been synthesised with a wide variety of complex inorganic anions trapped in a large, flexible, one-dimensional pore, with anions including chloride, bromide,...

Cyclization reactions of homopropargyl azide derivatives catalyzed by PtCl4 in ethanol solution: synthesis of functionalized pyrrole derivatives.

Org. Lett. 8(23) , 5349-52, (2006)

[Structure: see text] PtCl4-catalyzed cyclization reactions of homopropargyl azide derivatives to pyrrole rings were investigated. Using ethanol as solvent with 2,6-di-tert-butyl-4-methylpyridine as t...

Mutagenicity of cadmium, platinum and rhodium compounds in cultured mammalian cells.

Gifu Shika Gakkai Zasshi 17(2) , 575-81, (1990)

The induction of mutation by cadmium chloride (CdCl2), platinum tetrachloride (PtCl4), and rhodium trichloride (RhCl3.3H2O) was measured utilizing the hypoxanthine-guanine phosphoribosyl transferase (...

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