蒽醌-1,5-二磺酸

蒽醌-1,5-二磺酸用途

是染料中间体，用于制蒽醌型分散染料、酸性染料和还原染料，如分散蓝2BLN和酸性蒽醌天蓝等

蒽醌-1,5-二磺酸名称

[ CAS 号 ]:
117-14-6

[ 中文名 ]:
蒽醌-1,5-二磺酸

[ 英文名 ]:
1,5-Anthraquinonedisulfonic acid

[中文别名 ]:

蒽醌-1,5-二磺酸

[英文别名 ]:

1,6-anthraquinonedisulfonate
1,5-ANTHRAQUINONEDISULFONIC ACID
anthraquinone disulfonic acid
EINECS 204-177-7
anthraquinone-1,5-disulphonic acid
1,5-anthraquinone disulfonate
1,5-anthraquinonesulfonic acid
anthraquinone-1,5-disulfonic acid
1,5-Disulfoanthraquinone
9,10-Dioxoanthracene-1,5-disulphonic acid

蒽醌-1,5-二磺酸物理化学性质

[ 密度 ]:
1.8 g/cm3

[ 熔点 ]:
310-311ºC

[ 分子式 ]:
C₁₄H₈O₈S₂

[ 分子量 ]:
368.33900

[ 精确质量 ]:
367.96600

[ PSA ]:
159.64000

[ LogP ]:
3.11700

[ 折射率 ]:
1.705

[ 储存条件 ]:
库房通风低温干燥

蒽醌-1,5-二磺酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CB0553000

CHEMICAL NAME :: 1,5-Anthracenedisulfonic acid, 9,10-dihydro-9,10-dioxo-

CAS REGISTRY NUMBER :: 117-14-6

BEILSTEIN REFERENCE NO. :: 2180499

LAST UPDATED :: 199701

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C14-H8-O8-S2

MOLECULAR WEIGHT :: 368.34

WISWESSER LINE NOTATION :: L C666 BV IVJ DSWQ KSWQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2357 mg/kg

TOXIC EFFECTS :: Liver - liver function tests impaired Kidney, Ureter, Bladder - renal function tests depressed

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(3),73,1980

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2357 mg/kg

TOXIC EFFECTS :: Liver - liver function tests impaired Kidney, Ureter, Bladder - renal function tests depressed

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(3),73,1980

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 5500 mg/kg

TOXIC EFFECTS :: Liver - liver function tests impaired Kidney, Ureter, Bladder - renal function tests depressed

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(3),73,1980

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 2357 mg/kg

TOXIC EFFECTS :: Liver - liver function tests impaired Kidney, Ureter, Bladder - renal function tests depressed

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(3),73,1980 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5303 mg/kg/45D-I

TOXIC EFFECTS :: Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Blood - changes in erythrocyte (RBC) count Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 45(3),73,1980 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82070 No. of Facilities: 28 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 308 (estimated)

蒽醌-1,5-二磺酸安全信息

[ 海关编码 ]:
2914399090

蒽醌-1,5-二磺酸合成路线

详细合成路线

蒽醌-1,5-二磺酸上下游产品

蒽醌-1,5-二磺酸上游产品

蒽醌-1,5-二磺酸下游产品

蒽醌-1,5-二磺酸制备

以蒽醌为原料，在硫酸汞存在下分步磺化，同时生成1,5-二磺酸和1,8-二磺酸，所得磺化物用硫酸稀释，利用其在硫酸中的溶解度不同而进行分离。操作示例在磺化锅内加入蒽醌270kg和34%发烟硫酸630kg（内含有2.7kg金属汞），加热至120-125℃，保温4h。保温毕，降温至100℃，加入96%硫酸180kg。加完后，将料压到搪玻璃锅内。在75℃加入78%硫酸360kg，于1h加完，4h内降温到55℃，保温1h，使蒽醌-1,5-二磺酸完全析出。过滤，滤饼用78%硫酸240L分二次洗涤。滤饼为蒽醌-1,5-二磺酸成品。滤液及洗液合并，供生产蒽醌1,8-二磺酸用。原料消耗定额：蒽醌（98%）1498kg/t、硫酸（65%）1206kg/t、发烟硫酸（SO320%）2407kg/t。

蒽醌-1,5-二磺酸海关

[ 海关编码 ]: 2914399090

[ 中文概述 ]:
2914399090. 其他不含其他含氧基的芳香酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%