(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl structure
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Common Name | (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl | ||
|---|---|---|---|---|
| CAS Number | 99646-28-3 | Molecular Weight | 678.779 | |
| Density | N/A | Boiling Point | 754.4±60.0 °C at 760 mmHg | |
| Molecular Formula | C48H40P2 | Melting Point | 255-257 °C | |
| MSDS | USA | Flash Point | 438.8±39.2 °C | |
| Name | (s)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl |
|---|---|
| Synonym | More Synonyms |
| Boiling Point | 754.4±60.0 °C at 760 mmHg |
|---|---|
| Melting Point | 255-257 °C |
| Molecular Formula | C48H40P2 |
| Molecular Weight | 678.779 |
| Flash Point | 438.8±39.2 °C |
| Exact Mass | 678.260498 |
| PSA | 27.18000 |
| LogP | 15.22 |
| Vapour Pressure | 0.0±2.4 mmHg at 25°C |
| Hazard Codes | Xi: Irritant; |
|---|---|
| Risk Phrases | R36/37/38:Irritating to eyes, respiratory system and skin . |
| Safety Phrases | S37/39-S26 |
| RIDADR | NONH for all modes of transport |
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~94%
(R)-(+)-2,2'-Bi... CAS#:99646-28-3 |
| Literature: Wu, Hai-Chen; Yu, Jin-Quan; Spencer, Jonathan B. Organic Letters, 2004 , vol. 6, # 25 p. 4675 - 4678 |
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~66%
(R)-(+)-2,2'-Bi... CAS#:99646-28-3 |
| Literature: Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831 |
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~45%
(R)-(+)-2,2'-Bi... CAS#:99646-28-3 |
| Literature: Liu, Lei; Wu, Hai-Chen; Yu, Jin-Quan Chemistry - A European Journal, 2011 , vol. 17, # 39 p. 10828 - 10831 |
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~%
(R)-(+)-2,2'-Bi... CAS#:99646-28-3 |
| Literature: Journal of Organic Chemistry, , vol. 51, # 5 p. 629 - 635 |
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~%
(R)-(+)-2,2'-Bi... CAS#:99646-28-3 |
| Literature: Journal of Organic Chemistry, , vol. 51, # 5 p. 629 - 635 |
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Catalytic Approach for the Formation of Optically Active Allyl alpha-Amino Acids by Addition of Allylic Metal Compounds to alpha-Imino Esters.
J. Org. Chem. 64(13) , 4844-4849, (1999) A new catalytic enantioselective approach for the formation of allyl alpha-amino acid derivatives by reaction of N-tosyl alpha-imino esters with allyl stannanes and silanes catalyzed by chiral copper(... |
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Catalytic Asymmetric Aldol Reaction of Trimethoxysilyl Enol Ethers Using 2, 2'-Bis (di-p-tolylphosphino)-1, 1'-binaphthyl AgF Complex. Yanagisawa A, et al.
Bull. Chem. Soc. Jpn. 74(8) , 1477-84, (2001)
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Asymmetric hydroformylation of vinyl acetate with BINAP-rhodium (I) complexes. Hoegaerts D and Jacobs PA.
Tetrahedron Asymmetry 10(15) , 3039-43, (1999)
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| (S)-(-)-2,2‘-Bis(di-p-tolylphosphino)-1,1‘-binaphthyl |
| 1,1'-Binaphthalene-2,2'-diylbis[bis(4-methylphenyl)phosphine] |
| Phosphine, 1,1'-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)- |
| MFCD00269856 |
| (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL |
| (S)-(-)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl |
| (S)-(-)-TolBINAP |
| (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl |