methylpropiolate structure 
             | 
        Common Name | methylpropiolate | ||
|---|---|---|---|---|
| CAS Number | 922-67-8 | Molecular Weight | 84.073 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 104.0±9.0 °C at 760 mmHg | |
| Molecular Formula | C4H4O2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 10.0±0.0 °C | |
| Symbol | 
             
            
             
            
            GHS02, GHS07  | 
        Signal Word | Danger | |
| Name | Methyl propiolate | 
|---|---|
| Synonym | More Synonyms | 
| Density | 1.0±0.1 g/cm3 | 
|---|---|
| Boiling Point | 104.0±9.0 °C at 760 mmHg | 
| Molecular Formula | C4H4O2 | 
| Molecular Weight | 84.073 | 
| Flash Point | 10.0±0.0 °C | 
| Exact Mass | 84.021126 | 
| PSA | 26.30000 | 
| LogP | 0.89 | 
| Vapour Pressure | 31.4±0.2 mmHg at 25°C | 
| Index of Refraction | 1.408 | 
| Storage condition | Refrigerator (+4°C) + Flammables area | 
| Stability | Stable. Highly flammable. Incompatible with strong oxidizing agents, bases, acids. | 
                                    CHEMICAL IDENTIFICATION
 
 
 
 
 
 
 
 
 HEALTH HAZARD DATAACUTE TOXICITY DATA
 
 
 
 
 
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| Symbol | 
                                    
                                     
                                    
                                     
                                    
                                    GHS02, GHS07  | 
                            
|---|---|
| Signal Word | Danger | 
| Hazard Statements | H225-H315-H319-H335 | 
| Precautionary Statements | P210-P261-P305 + P351 + P338 | 
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter | 
| Hazard Codes | F:Flammable;Xi:Irritant; | 
| Risk Phrases | R11;R36/37/38 | 
| Safety Phrases | S26-S36-S36/37/39-S23-S16 | 
| RIDADR | UN 3272 3/PG 2 | 
| WGK Germany | 3 | 
| RTECS | UE0050000 | 
| Packaging Group | II | 
| Hazard Class | 3 | 
| HS Code | 29161980 | 
| Precursor 8 | |
|---|---|
| DownStream 10 | |
| HS Code | 2916190090 | 
|---|---|
| Summary | 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0% | 
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                                    Predator lipids induce paralytic shellfish toxins in bloom-forming algae.
                                    
                                    
                                     Proc. Natl. Acad. Sci. U. S. A. 112 , 6395-400, (2015) Interactions among microscopic planktonic organisms underpin the functioning of open ocean ecosystems. With few exceptions, these organisms lack advanced eyes and thus rely largely on chemical sensing...  | 
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                                    Determination of glutathione in baker's yeast by capillary electrophoresis using methyl propiolate as derivatizing reagent.
                                    
                                    
                                     J. Chromatogr. A. 1300 , 204-8, (2013) In this study we demonstrate - for the first time - the suitability of methyl propiolate - an alkylester of propiolic acid - as a thiol derivatizing reagent for capillary electrophoresis. Glutathione ...  | 
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                                    Synthesis of tetrahydropyrimidin-2-ones via FeCl3 catalyzed one-pot domino reaction of amines, methyl propiolate, aromatic aldehydes, and urea.
                                    
                                    
                                     Mol. Divers. 18(1) , 79-89, (2014) Polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives could be selectively produced from the one-pot domino reaction of arylamines, methyl propiolate, aromatic aldehydes, and u...  | 
                                
| Methyl propiolate | 
| Propynoic acid, methyl ester | 
| EINECS 213-083-5 | 
| methyl prop-2-ynoate | 
| methylpropiolate | 
| Propynoic acid methyl ester | 
| 2-Propynoic acid, methyl ester (9CI) | 
| Methyl acetylenecarboxylate | 
| Methyl propynoate | 
| MFCD00008572 | 
| 2-Propynoic acid, methyl ester |