(2R)-1-(benzyloxy)propan-2-ol

Modify Date: 2024-01-02 07:26:49

(2R)-1-(benzyloxy)propan-2-ol Structure
(2R)-1-(benzyloxy)propan-2-ol structure
Common Name (2R)-1-(benzyloxy)propan-2-ol
CAS Number 89401-28-5 Molecular Weight 166.217
Density 1.0±0.1 g/cm3 Boiling Point 263.8±15.0 °C at 760 mmHg
Molecular Formula C10H14O2 Melting Point N/A
MSDS Chinese USA Flash Point 108.2±14.6 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name (2R)-1-phenylmethoxypropan-2-ol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 263.8±15.0 °C at 760 mmHg
Molecular Formula C10H14O2
Molecular Weight 166.217
Flash Point 108.2±14.6 °C
Exact Mass 166.099380
PSA 29.46000
LogP 1.73
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.518

 MSDS


Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
: (R)-(−)-1-Benzyloxy-2-propanol
Product name

Section2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
According to Regulation (EC) No1272/2008
Acute toxicity, Oral (Category 4)
Skin irritation (Category 2)
Eye irritation (Category 2)
Specific target organ toxicity - single exposure (Category 3)
According to European Directive 67/548/EEC as amended.
Harmful if swallowed. Irritating to eyes, respiratory system and skin.
Label elements
Pictogram
Signal wordWarning
Hazard statement(s)
H302Harmful if swallowed.
H315Causes skin irritation.
H319Causes serious eye irritation.
H335May cause respiratory irritation.
Precautionary statement(s)
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Hazard symbol(s)
XnHarmful
R-phrase(s)
R22Harmful if swallowed.
R36/37/38Irritating to eyes, respiratory system and skin.
S-phrase(s)
S26In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36Wear suitable protective clothing.
Other hazards - none

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms: (R)-1-O-Benzylpropylene glycol
Formula: C10H14O2
Molecular Weight: 166,22 g/mol
CAS-No.EC-No.Index-No.ClassificationConcentration
(R)-(-)-1-Benzyloxy-2-propanol
89401-28-5--Acute Tox. 4; Skin Irrit. 2; Eye-
Irrit. 2; STOT SE 3; H302,
H315, H319, H335
Xn, R22 - R36/37/38
For the full text of the H-Statements mentioned in this Section, see Section 16.

Section4. FIRST AID MEASURES
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Normal measures for preventive fire protection.
Conditions for safe storage
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Recommended storage temperature: 2 - 8 °C

Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protective equipment
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with
multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to
engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Hand protection
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN 374 derived from it.
Handle with gloves.
Eye protection
Face shield and safety glasses
Skin and body protection
Choose body protection according to the amount and concentration of the dangerous substance at the
work place.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Formliquid
Colourcolourless
Safety data
pH no data available
Melting pointno data available
Boiling pointno data available
Flash point> 109,9 °C
Ignition temperature no data available
Lower explosion limit no data available
Upper explosion limit no data available
Density1,027 g/cm3 at 25 °C
Water solubilityno data available
Partition coefficient: log Pow: 1,621
n-octanol/water

Section10. STABILITY AND REACTIVITY
Chemical stability
Stable under recommended storage conditions.
Conditions to avoid
no data available
Materials to avoid
Strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides

Section11. TOXICOLOGICAL INFORMATION
Acute toxicity
no data available
Inhalation: no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
InhalationMay be harmful if inhaled. Causes respiratory tract irritation.
IngestionHarmful if swallowed.
SkinMay be harmful if absorbed through skin. Causes skin irritation.
EyesCauses eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.
Additional Information
RTECS: no data available

Section12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
no data available

Section13. DISPOSAL CONSIDERATIONS
Product
Observe all federal, state, and local environmental regulations. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn
in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

Section14. TRANSPORT INFORMATION
ADR/RID
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods



SECTION 15 - REGULATORY INFORMATION
N/A


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn: Harmful;
Risk Phrases 22-36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
WGK Germany 3.0
HS Code 2909499000

 Synthetic Route

~%

(2R)-1-(benzyloxy)propan-2-ol Structure

(2R)-1-(benzylo...

CAS#:89401-28-5

Literature: Acta chemica Scandinavica (Copenhagen, Denmark : 1989), , vol. 48, # 6 p. 506 - 510

 Precursor & DownStream

Precursor  1

DownStream  0

 Customs

HS Code 2909499000
Summary 2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

 Synonyms

(R)-1-(Benzyloxy)propan-2-ol
MFCD07367007
(S)-1-(benzyloxy)propan-2-ol
(2R)-1-(Benzyloxy)-2-propanol
2-Propanol, 1-(phenylmethoxy)-, (2R)-
(S)-(+)-1,2-Propanediol 1-benzyl ether
(R)-1-O-Benzylpropylene glycol
(2R)-1-(benzyloxy)propan-2-ol
(s)-(-)-1-Benzyloxy-2-propanol
(2S)-1-benzyloxypropan-2-ol
(R)-(-)-1-Benzyloxy-2-propanol
2-Propanol,1-(phenylmethoxy)-,(2R)