5-bromo-2-ethoxybenzaldehyde

Modify Date: 2024-01-07 17:41:30

5-bromo-2-ethoxybenzaldehyde Structure
5-bromo-2-ethoxybenzaldehyde structure
Common Name 5-bromo-2-ethoxybenzaldehyde
CAS Number 79636-94-5 Molecular Weight 229.07100
Density 1.451 g/cm3 Boiling Point 302.7ºC at 760 mmHg
Molecular Formula C9H9BrO2 Melting Point 68-71 °C(lit.)
MSDS N/A Flash Point 136.9ºC

 Names

Name 5-bromo-2-ethoxybenzaldehyde
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.451 g/cm3
Boiling Point 302.7ºC at 760 mmHg
Melting Point 68-71 °C(lit.)
Molecular Formula C9H9BrO2
Molecular Weight 229.07100
Flash Point 136.9ºC
Exact Mass 227.97900
PSA 26.30000
LogP 2.66030
Index of Refraction 1.573
Storage condition -20°C

 MSDS

Name: 5-Bromo-2-ethoxybenzaldehyde 98% Material Safety Data Sheet
Synonym:
CAS: 79636-94-5
Section 1 - Chemical Product MSDS Name:5-Bromo-2-ethoxybenzaldehyde 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
79636-94-5 5-Bromo-2-ethoxybenzaldehyde 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 79636-94-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Flakes
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 67 - 71 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C9H9BrO2
Molecular Weight: 229.07

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 79636-94-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
5-Bromo-2-ethoxybenzaldehyde - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 79636-94-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 79636-94-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 79636-94-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S37/39-S26
WGK Germany 3
HS Code 2913000090

 Synthetic Route

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5-bromo-2-ethoxybenzaldehyde Structure

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5-bromo-2-ethoxybenzaldehyde Structure

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CAS#:79636-94-5

Literature: Kralj, Ana; Nguyen, Mai-Thao; Tschammer, Nuska; Ocampo, Nicolette; Gesiotto, Quinto; Heinrich, Markus R.; Phanstiel, Otto Journal of Medicinal Chemistry, 2013 , vol. 56, # 12 p. 5019 - 5032

~51%

5-bromo-2-ethoxybenzaldehyde Structure

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CAS#:79636-94-5

Literature: Bhatt, Vivekanada M.; Perumal, Thirumalai P. Tetrahedron Letters, 1981 , vol. 22, # 27 p. 2605 - 2608

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5-bromo-2-ethoxybenzaldehyde Structure

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Literature: US5593993 A1, ;

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5-bromo-2-ethoxybenzaldehyde Structure

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CAS#:79636-94-5

Literature: Justus Liebigs Annalen der Chemie, , vol. 145, p. 302 Journal of the Chemical Society, , vol. 55, p. 550

 Customs

HS Code 2913000090
Summary HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

 Synonyms

2-ethoxy-5-bromobenzaldehyde
2-Aethoxy-5-brom-benzaldehyd
5-bromo-2-ethoxy benzaldehyde
MFCD00016600