D149 Dye

Modify Date: 2024-01-02 09:10:49

D149 Dye Structure
D149 Dye structure
Common Name D149 Dye
CAS Number 786643-20-7 Molecular Weight 741.94000
Density 1.47g/cm3 Boiling Point N/A
Molecular Formula C42H35N3O4S3 Melting Point N/A
MSDS USA Flash Point N/A

 Use of D149 Dye


D149 Dye is an indoline-based dye, which is a high-extinction-coefficient metal-free organic sensitizer.

 Names

Name D-149 Dye
Synonym More Synonyms

 D149 Dye Biological Activity

Description D149 Dye is an indoline-based dye, which is a high-extinction-coefficient metal-free organic sensitizer.
Related Catalog
In Vitro D149 is a metal-free organic dye, which is promising all-organic alternatives. D149 displays power conversion efficiency of up to 9%. Furthermore, D149 has a peak extinction co-efficient of 68700 M-1 cm-1 at 540 nm, significantly higher than 13900 M-1cm-1 at 535 nm for N719[1]. D149, a metal-free indoline dye, is one of the most promising sensitizers for dye-sensitized solar cells (DSSCs) and has shown very high solar energy conversion efficiencies of 9%. D149 shows a large number of unresolved aromatic and olefinic signals between 7 and 7.5 ppm[2]
Cell Assay The porous TiO2 films are immersed in a 0.5 mM D149 (1-material) dye solution in a 1:1 (v/v) mixture of acetonitrile (HPLC) and tert-butanol (LR) overnight once their temperature decreased to approximately 110°C. The samples are then taken out of the dye bath, washed with acetonitrile, and dried. The working electrode and Pt counter electrode [produced using a pre-drilled piece of 2.3 mm FTO glass, coated with one drop of 10 mM platinic acid solution [H2PtCl6] and heated to 400°C for 20 min] are assembled into a sandwich type cell and sealed with a spacer of 25 μm Surlyn. An I-1/I3-1 organic solvent based electrolyte solution [50 mM iodine, 0.6 M 1,2-dimethyl-3-propylimidazelium iodide, 0.1 M lithium iodide in methoxypropionitrile] is introduced via vacuum back-filling. The hole is sealed with a piece of aluminium foil-backed Surlyn[1].
References

[1]. Lin J, et al. 3D hierarchical rutile TiO2 and metal-free organic sensitizer producing dye-sensitized solar cells 8.6% conversion efficiency. Sci Rep. 2014 Aug 29;4:5769.

[2]. El-Zohry A, et al. Isomerization and Aggregation of the Solar Cell Dye D149. J Phys Chem C Nanomater Interfaces. 2012 Dec 20;116(50):26144-26153.

 Chemical & Physical Properties

Density 1.47g/cm3
Molecular Formula C42H35N3O4S3
Molecular Weight 741.94000
Exact Mass 741.17900
PSA 168.48000
LogP 7.19120
Storage condition -20℃

 Safety Information

RIDADR NONH for all modes of transport

 Articles2

More Articles
High efficiency of dye-sensitized solar cells based on metal-free indoline dyes.

J. Am. Chem. Soc. 126 , 12218, (2004)

We now report metal-free organic dyes having a new type of indoline structure, which exhibits high efficiencies in dye-sensitized solar cells. The solar energy to current conversion efficiencies with ...

S. Itoh et. al.

Adv. Mater. 18 , 1202, (2006)

 Synonyms

D149 Dye